Activated rate processes: a multidimensional Kramers turnover theory

Autor: Eli Hershkowitz, Eli Pollak
Rok vydání: 1994
Předmět:
Zdroj: Chemical Physics. 180:191-197
ISSN: 0301-0104
DOI: 10.1016/0301-0104(93)e0425-u
Popis: The turnover theory for activated rate processes is generalized to include multidimensional strongly coupled systems. A uniform expression for the rate, valid for all damping values is derived and applied to numerical simulations results of Straub and Berne. The theory is applicable to both space and time dependent friction.
Databáze: OpenAIRE