Laser raman spectra of the uranium hexachloride molecule and anions (UCl6, UCl6−1 and UCl6−2)

Autor:	Jacob Shamir, Atara Silberstein
Rok vydání:	1975
Předmět:	Valence (chemistry) Polymers and Plastics Octahedral symmetry Analytical chemistry chemistry.chemical_element Uranium Spectral line symbols.namesake chemistry.chemical_compound Uranium hexachloride chemistry Materials Chemistry symbols Molecule Raman spectroscopy Raman scattering
Zdroj:	Journal of Inorganic and Nuclear Chemistry. 37:1173-1175
ISSN:	0022-1902
DOI:	10.1016/0022-1902(75)80464-7
Popis:	Uranium hexachloride species in which the uranium is in the three, different VI, V and IV oxidation states were synthesized and their laser Raman spectra studied. The various spectra of UCl6, UCl6−1 and UCl6−2 show a similar pattern of three lines. These were assigned as ν1, ν2 and ν5, the Raman active vibrations of an octahedral symmetry −Oh. The changes in the frequencies of the respective vibrations were correlated with changes in oxidation states of uranium and with the counter cations in the various salts.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::fb798af5f141e771e3353a5fecdaeac7 https://doi.org/10.1016/0022-1902(75)80464-7 Zobrazit plný text záznamu