Synthesis and characterisation of tetrazole compounds: 3 series of new ligands representing versatile building blocks for iron(II) spin-crossover compounds
| Autor: | C. Matthias Grunert, Johannes Schweifer, Peter Weinberger, Christina Hampel, Wolfgang Linert, Kurt Mereiter, Arno F. Stassen |
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| Rok vydání: | 2005 |
| Předmět: |
chemistry.chemical_classification
Organic Chemistry Supramolecular chemistry Spin transition Crystal structure Polymer Nuclear magnetic resonance spectroscopy Analytical Chemistry Inorganic Chemistry chemistry.chemical_compound Crystallography chemistry Spin crossover Tetrazole Single crystal Spectroscopy |
| Zdroj: | Journal of Molecular Structure. 733:41-52 |
| ISSN: | 0022-2860 |
| DOI: | 10.1016/j.molstruc.2004.07.036 |
| Popis: | New tetrazole compounds were synthesized and characterised by NMR and FTIR spectroscopy as well as by single crystal X-ray diffraction. We present in this paper mono- and ditetrazoles, which represent a versatile class of building blocks for the formation of mononuclear iron(II) complexes with monotetrazoles as terminal ligands as well as iron(II) coordination polymers with ditetrazoles as bridging ligands. Especially, the series of α,ω-bis[tetrazol-1-yl]-alkanes open the field of fascinating supramolecular structures with spin transition properties. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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