Compounds Based on the Vanadyl Formate Double Layer
| Autor: | T. R. Gilson |
|---|---|
| Rok vydání: | 1995 |
| Předmět: |
Formic acid
Inorganic chemistry Infrared spectroscopy Crystal structure Condensed Matter Physics Electronic Optical and Magnetic Materials Inorganic Chemistry chemistry.chemical_compound Crystallography symbols.namesake chemistry Materials Chemistry Ceramics and Composites symbols Formate Carboxylate Physical and Theoretical Chemistry Raman spectroscopy Hydrate Fluoride |
| Zdroj: | Journal of Solid State Chemistry. 117:136-144 |
| ISSN: | 0022-4596 |
| DOI: | 10.1006/jssc.1995.1256 |
| Popis: | New compounds, based on the interpenetrating double layers found in oxo-vanadium (IV) formate monohydrate, VO(HCO2)2 · H2O, have been synthesized. Ligand water is replaced by formic acid in VO(HCO2)2 · HCO2H, or by interlayer bridging fluoride with additional (NH4 or K) cations in [VO(HCO2)2]2 · NH4F · NH4OH, [VO(HCO2)2]2 · KF · NH4OH, and [VO(HCO2)2]2 · KF · 1 2 KOH. Indexed XRPD for the layer compounds and vibrational (IR and Raman) data including those for the related chain polymer K2VO(HCO2)2 are given. Parallels are drawn with the lamellar phase vanadyl phosphates and arsenates. |
| Databáze: | OpenAIRE |
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