A dual supramolecular crosslinked polyurethane with superior mechanical properties and autonomous self-healing ability

Autor:	Yan Zhou, Haohao Wu, Yuming Yang, Xiangdong Liu, Haopu Xie, Yinglu Sun, Shaobin Xu, Dekun Sheng, Xinxin Tian
Rok vydání:	2020
Předmět:	Toughness chemistry.chemical_compound Chemistry Self-healing Ultimate tensile strength Materials Chemistry Supramolecular chemistry General Chemistry Composite material Catalysis Polyurethane
Zdroj:	New Journal of Chemistry. 44:7395-7400
ISSN:	1369-9261 1144-0546
DOI:	10.1039/c9nj05446d
Popis:	To prepare a robust material with high self-healing capability under ambient conditions is still a great challenge. Herein, a novel self-healing polyurethane is developed via a dual-dynamic network design, in which multiple H-bonding and metal-coordinated bonds (zinc–imidazole interaction) were incorporated into a polyurethane matrix. Benefiting from the dual-dynamic network, the synthesized metallopolymers exhibit excellent mechanical properties, such as high tensile strength (from 6.68 MPa to 14.38 MPa), excellent stretchability (about 2000%) and superior toughness (from 55.61 MJ m−3 to 96.21 MJ m−3). Moreover, these metallopolymers show good self-healing capability. After healing under ambient conditions for 48 hours, the tensile strength and strain at break of PU-IZ/Zn-0.50 can reach up to 7.13 MPa and 1800%, respectively. The dual-dynamic crosslinked metallopolymers might provide a novel approach to design tough and self-healable materials for various industrial applications.
Databáze:	OpenAIRE
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