ChemInform Abstract: Siliranes: Formation, Isonitrile Insertions, and Thermal Rearrangements

Autor:	Stefan Willms, Wolfang Saak, Siegfried Pohl, Heinrich Marsmann, Edwin Kroke, Manfred Weidenbruch
Rok vydání:	2010
Předmět:	Crystallography chemistry.chemical_compound Chemistry Thermal decomposition Polymer chemistry Silylene General Medicine
Zdroj:	ChemInform. 27
ISSN:	0931-7597
DOI:	10.1002/chin.199638175
Popis:	The siliranes 7–10 and 22 as well as the vinylsiliranes 14–16, 20 , and 21 are prepared by [1+2]-cycloadditions of silylene 2 with alkenes and dienes. The first isonitrile insertion products, the silacyclobutanimines 26–28 were synthesized and the structure of 28 was determined by X-ray crystallography. Upon thermolysis 20–22 rearranged quantitatively to furnish the compounds 29–32 .
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::fb3094fa1b66a15b95976c8d2e4e8677 https://doi.org/10.1002/chin.199638175 Zobrazit plný text záznamu Plný text