1D Water cages in a double-walled framework based on cubic [Ni4(µ3-OH)4] units: Synthesis, structure, and magnetism
| Autor: | Yu-Fei Wang, Yuan-Chun He, Long-Wei Huang, Xin-Meng Jia, Zhong-Lin Li, Jinmao You, Xiao-Qing Yan, Fang-Hua Zhao |
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| Rok vydání: | 2019 |
| Předmět: |
Double walled
Materials science Magnetism Hydrothermal reaction chemistry.chemical_element 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences 0104 chemical sciences Electronic Optical and Magnetic Materials Inorganic Chemistry Crystallography Nickel Ferromagnetism chemistry Thermal Materials Chemistry Ceramics and Composites Water cluster Physical and Theoretical Chemistry 0210 nano-technology |
| Zdroj: | Journal of Solid State Chemistry. 271:309-313 |
| ISSN: | 0022-4596 |
| DOI: | 10.1016/j.jssc.2019.01.013 |
| Popis: | The hydrothermal reaction of NiSO4·6H2O and 4,4′-bis(1-imidazolyl)bipheny (bibp) has afforded a new nickel complex, {[Ni4(µ3-OH)4(µ4-SO4)(bibp)4](OH)2·12H2O}n (1). The Ni(II) centers are bridged by µ3-OH- anions into cubic [Ni4(µ3-OH)4] units, which are connected by bibp ligands and µ4-SO42- anions into a double-walled 3D framework with channels along c direction. Unusual 1D water cages with a repeat of vase-like water cluster are trapped in the channels. Magnetic studies reveal ferromagnetic behavior for complex 1, and the thermal property of 1 was also studied. |
| Databáze: | OpenAIRE |
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