Use of Molecularly Imprinted Polymer for the Preconcentration of 4-Nitrophenol from Aqueous Media

Autor:	Yu. S. Frolova, P. T. Sukhanov, A. S. Gubin, E. D. Proskuryakova, N. Yu. Sannikova
Rok vydání:	2019
Předmět:	chemistry.chemical_classification Sorbent Aqueous solution Aqueous medium Chemistry 010401 analytical chemistry Molecularly imprinted polymer 4-Nitrophenol Polymer 010402 general chemistry 01 natural sciences 0104 chemical sciences Analytical Chemistry chemistry.chemical_compound Chemical engineering Particle size Selectivity
Zdroj:	Journal of Analytical Chemistry. 74:11-17
ISSN:	1608-3199 1061-9348
DOI:	10.1134/s1061934819070116
Popis:	A method is developed for the modification of Fe3O4 particles with a polymer based on N-vinylpyrrolidone with molecular imprints of 4-nitrophenol. The conditions for sorbent synthesis are justified, i.e., the ratio of the crosslinking agent to the functional monomer, as well as the of template to the functional monomer. The particle size of the sorbent was about 100 nm. An installation for the preconcentration of 4‑nitrophenol from aqueous solutions under dynamic conditions is proposed. 96% recovery at 100-fold preconcentration is achieved. The selectivity of the obtained polymer is studied. The imprinting factor in relation to 4-nitrophenol was 3.8.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::fb1b3554952f9fd50fd975ce9813ea6d https://doi.org/10.1134/s1061934819070116 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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