The reaction of iron carboxylates with titanium alkoxides. Isolation and structural characterisation of [Ti6(μ3-O)6(O2CPh)6(OCH2C(CH3)3)6]

Autor:	Christopher M. Kepert, B.O. West, Leone Spiccia, Stuart Robert Batten, Adrian M. B. van den Bergen, Paul S. Ammala
Rok vydání:	2003
Předmět:	Inorganic Chemistry chemistry.chemical_compound chemistry Alkoxide Inorganic chemistry Polymer chemistry Materials Chemistry chemistry.chemical_element Carboxylate Physical and Theoretical Chemistry Toluene Bimetallic strip Titanium
Zdroj:	Inorganica Chimica Acta. 353:75-81
ISSN:	0020-1693
Popis:	The reaction of [Fe4(μ3-O)2(O2CPh)8(py)2] (1) with Ti(OPrn)4 in toluene yields separate Fe and Ti species each containing both carboxylate and alkoxide groups rather than a bimetallic FeTi complex. The addition of neopentanol to the reaction mixture has enabled [Ti6(μ3-O)6(O2CPh)6(OCH2C(CH3)3)6] (3) to be isolated and structurally identified. The compound [Ti6(μ3-O)4(O2CPh)8(OPrn)8] (4) has also been characterised and shown not to convert to a {Ti6(μ3-O)6}12+ core compound under the same temperature conditions used in the FeTi reactions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::fb08038ac175994540c085708d06e3a3 https://doi.org/10.1016/s0020-1693(03)00242-1 Zobrazit plný text záznamu Full Text from ScienceDirect