Radiolytic synthesis of Pd–M (M=Ag, Au, Cu, Ni and Pt) alloy nanoparticles and their use in reduction of 4-nitrophenol

Autor:	Mi-Ran Kim, Kwang-Pill Lee, Kim Sang-Ho, Jong-Han Chun, Anantha Iyengar Gopalan, Chul-Gyun Hwang, Oh Ji Hoon, Seong-Ho Choi, Seong-Dae Oh
Rok vydání:	2008
Předmět:	Aqueous solution Materials science Polyvinylpyrrolidone General Chemical Engineering Alloy Nanoparticle 4-Nitrophenol engineering.material Colloid Crystallography chemistry.chemical_compound chemistry Transmission electron microscopy Radiolysis medicine engineering Nuclear chemistry medicine.drug
Zdroj:	Journal of Industrial and Engineering Chemistry. 14:687-692
ISSN:	1226-086X
DOI:	10.1016/j.jiec.2008.04.008
Popis:	Polyvinylpyrrolidone, PVP, stabilized Pd–M (M = Ag, Au, Cu, Ni and Pt) alloy colloids are successfully prepared by γ-irradiation in aqueous solution. PVP-stabilized Pd–M colloids are characterized by field-emission transmission electron microscopy (FE-TEM) and energy dispersive X-ray spectroscopy (EDXS). The catalytic efficiency of Pd and Pd–M alloy colloids is analyzed for the reduction of 4-nitrophenol in aqueous solution at room temperature. The catalytic efficiency of Pd–M alloy nanoparticles takes the following order: Pd > Pd–Cu ∼ Pd–Ni > Pd–Ag ∼ Pd–Au > Pd–Pt.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::faee8b03cfe77bb3bfcd29995ef4050c https://doi.org/10.1016/j.jiec.2008.04.008 Zobrazit plný text záznamu Full Text from ScienceDirect