Reaction of pyrocatecholhalophosphoranes with phenylacetylene as a simple method for the preparation of functionally substituted cyclic quasiphosphonium ylids

Autor:	I. V. Konovalova, A. N. Pudovik, P. P. Chernov, Vladimir F. Mironov, E. I. Gol'dfarb
Rok vydání:	1990
Předmět:	chemistry.chemical_compound 13c nmr spectroscopy Phenylacetylene Chemistry Stereochemistry General Chemistry Triple bond Medicinal chemistry
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 39:1319-1319
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00962417
Popis:	Phosphoranes (I) and (II) also readily undergo addition at the triple bond in phenylacetylene to give functionally substituted quasiphosphonium ylids (III) and (IV), which have been previously obtained only with difficulty. Ylids (III) and (IV) are crystalline compounds with 31p NMR signals at 9 (III) and 18 ppm (IV). The structure of these compounds were also supported by IH, IH-{31P}, and 13C NMR spectroscopy. The composition was supported by elemental analysis.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::fae71fe3b3b25da2e217e44b3e2dd30f https://doi.org/10.1007/bf00962417 Zobrazit plný text záznamu Full text from SpringerLink