Application of Fe3O4@SiO2@sulfamic acid magnetic nanoparticles as recyclable heterogeneous catalyst for the synthesis of imine and pyrazole derivatives in aqueous medium

Autor: M. M. Samieadel, Mohammad Ali Nasseri, Batol Zakerinasab, Hassan Hassani
Rok vydání: 2015
Předmět:
Zdroj: Research on Chemical Intermediates. 42:3169-3181
ISSN: 1568-5675
0922-6168
DOI: 10.1007/s11164-015-2204-1
Popis: Sulfamic acid supported on Fe3O4@SiO2 superpara magnetic nanoparticles was successfully applied as a recyclable solid acid catalyst with a large density of sulfamic acid groups for the synthesis of pyrazole derivatives, an important class of potentially bioactive compounds. The products are obtained in high yield from the one-pot reaction procedure involving dicarbonyl compounds and hydrazines/hydrazides. This new method totally avoids the use of toxic or expensive solvents and organic acids in this reaction.
Databáze: OpenAIRE