Application of Fe3O4@SiO2@sulfamic acid magnetic nanoparticles as recyclable heterogeneous catalyst for the synthesis of imine and pyrazole derivatives in aqueous medium
Autor: | M. M. Samieadel, Mohammad Ali Nasseri, Batol Zakerinasab, Hassan Hassani |
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Rok vydání: | 2015 |
Předmět: | |
Zdroj: | Research on Chemical Intermediates. 42:3169-3181 |
ISSN: | 1568-5675 0922-6168 |
DOI: | 10.1007/s11164-015-2204-1 |
Popis: | Sulfamic acid supported on Fe3O4@SiO2 superpara magnetic nanoparticles was successfully applied as a recyclable solid acid catalyst with a large density of sulfamic acid groups for the synthesis of pyrazole derivatives, an important class of potentially bioactive compounds. The products are obtained in high yield from the one-pot reaction procedure involving dicarbonyl compounds and hydrazines/hydrazides. This new method totally avoids the use of toxic or expensive solvents and organic acids in this reaction. |
Databáze: | OpenAIRE |
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