Solvent-induced allylic rearrangements in poly(trichlorobutadiene) chains

Autor:	T. A. Larina, Pavel V. Petrovskii, I. I. Vointseva, L. M. Gil'man, T. L. Lebedeva
Rok vydání:	1997
Předmět:	Solvent Allylic rearrangement chemistry.chemical_compound Chloroform chemistry Hydrogen Polymer chemistry Chlorine chemistry.chemical_element General Chemistry Nuclear magnetic resonance spectroscopy Photochemistry
Zdroj:	Russian Chemical Bulletin. 46:732-738
ISSN:	1573-9171 1066-5285
DOI:	10.1007/bf02495203
Popis:	It was established by Fourier-transform IR and1H NMR spectroscopy that a portion of the units of poly(1,1,2- and 1,2,3-trichlorobuta-1,3-diene) chains rearrange with migration of the allylic chlorine (1–4%) and allylic hydrogen (3–10%) under the influence of chloroform. Rearrangement with the migration of hydrogen under the influence of CDCl3, CCl4, and THF was also observed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::fab670937b117eab83626248ec1eab2c https://doi.org/10.1007/bf02495203 Zobrazit plný text záznamu Full text from SpringerLink