8.29 Spectroscopic Analysis: Diastereomeric Derivatization for Spectroscopy

Autor: Tony D. James, Steven D. Bull, Paul S. Fordred, Caroline D. Evans, Magdalena E. Powell
Rok vydání: 2012
Předmět:
DOI: 10.1016/b978-0-08-095167-6.00845-4
Popis: Chirality plays a central role in the world around us, with nature and scientists producing an ever-increasing number of chiral molecules that have a wide range of different applications. The word chirality is used as a term to describe a molecule whose enantiomers are non-superimposable on their mirror images. A chiral molecule that contains a single stereogenic center may exist in an enantiopure form or as a mixture of enantiomers in varying ratios. Enantiomers exhibit identical physical and chemical properties when present in an achiral environment; however, they often behave very differently when placed in a chiral environment. Many biologically active molecules such as proteins, nucleic acids, and sugars are chiral biopolymers that are constructed from homochiral building blocks.
Databáze: OpenAIRE