Reactivity of frustrated Lewis pairs with BOC protected diazocarboxylates: FLP capture of diazene

Autor:	Zahid Hussain, Yong-An Luo, Yile Wu, Zheng-Wang Qu, Stefan Grimme, Douglas W. Stephan
Rok vydání:	2023
Předmět:	Materials Chemistry Metals and Alloys Ceramics and Composites General Chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials
Zdroj:	Chemical Communications. 59:6191-6194
ISSN:	1364-548X 1359-7345
DOI:	10.1039/d3cc01571h
Popis:	Reactions of (tBuO2CN)2 with FLPs inducing loss of CH2CMe2; using strong bases [Hbase]2 [((C6F5)3BO2CN)2] are isolated whereas with weaker bases diazene derivatives are obtained.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::faa6425b4d5f4184455889c751057fce https://doi.org/10.1039/d3cc01571h Zobrazit plný text záznamu