The use of chiral solvents to distinguishmeso fromd or1 diastereoisomers

Autor: Raymond J. Abraham, T. M. Siverns
Rok vydání: 1973
Předmět:
Zdroj: Organic Magnetic Resonance. 5:253-254
ISSN: 1097-458X
0030-4921
DOI: 10.1002/mrc.1270050513
Popis: The 56·4 MHz 19F spectrum of a mixture of meso and dl 1,2-difluoro-1,2 dichloroethane in L-bornyl acetate resolved the 19F resonances of the separate d and l stereoisomers, thus identifying the dl spectrum, but not those of the meso isomer. These observations are considered with other examples of the use of chiral solvents to distinguish meso and dl isomers.
Databáze: OpenAIRE