ChemInform Abstract: Reactions of α,β-Unsaturated Ketone Acetals with Trimethylsilyl Cyanide and Trimethylsilyl Sulfides

Autor:	Teruaki Mukaiyama, Jeng S. Han, Masaaki Yamada, T. Soga, Haruhiro Takenoshita
Rok vydání:	2010
Předmět:	Propene Substitution reaction chemistry.chemical_classification chemistry.chemical_compound Chalcone Perchlorate chemistry Double bond Trimethylsilyl General Medicine Trimethylsilyl cyanide Isomerization Medicinal chemistry
Zdroj:	ChemInform. 22
ISSN:	0931-7597
Popis:	In the presence of a catalytic amount of trityl perchlorate, trimethylsilyl cyanide reacts with the dimethyl acetals of chalcone derivatives, with simultaneous double bond isomerization, to yield γ-methoxy-α,β-unsaturated carbonitriles. Trimethylsilyl sulfides react with dimethyl acetals derived from α,β-unsaturated ketones to yield 1,3-bis(alkylthio)propene derivatives under similar conditions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::faa0aa126d88ffa1c8424f299aff4046 https://doi.org/10.1002/chin.199131072 Zobrazit plný text záznamu Plný text