X-ray structures of heteroleptic zinc(II) complexes involving combinations of O,O′-dialkyldithiophosphato and bidentate N-donor ligands
| Autor: | Gabriel Demo, Jan Vícha, Josef Novosad, Lukáš Jeremias, Michal Babiak, Zdeněk Trávníček |
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| Rok vydání: | 2014 |
| Předmět: |
chemistry.chemical_classification
Denticity 010405 organic chemistry X-ray chemistry.chemical_element Salt (chemistry) Zinc 010402 general chemistry Condensed Matter Physics 01 natural sciences 0104 chemical sciences Inorganic Chemistry Crystal Bond length Bipyridine chemistry.chemical_compound Crystallography chemistry X-ray crystallography General Materials Science |
| Zdroj: | Zeitschrift für Kristallographie - Crystalline Materials. 229:537-542 |
| ISSN: | 2196-7105 2194-4946 |
| DOI: | 10.1515/zkri-2014-1736 |
| Popis: | The detailed X-ray structural elucidation of reaction products of a zinc(II) salt with O,O′-dialkyldithiophosphate and nitrogen-containing heterocycles (N–N=1,10-phenanthroline (phen) or 2,2′-bipyridine (bpy)) has been performed. Surprisingly, together with [Zn(S2 P(OR)2)2(N–N)] compounds, also ionic-type complexes having the formula of [Zn(N–N)3](S2 P(OR)2)2 have been obtained using the same molar ratios of the reactants. The prepared complexes have been characterized by elemental analysis and single-crystal X-ray analysis. The crystallographic analysis showed that the bond lengths and bite angles of the prepared complexes are in good agreement with those of similar compounds. The crystal packing of described complexes is formed via π–π stacking interactions and/or C–H···S non-covalent contacts. |
| Databáze: | OpenAIRE |
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