ChemInform Abstract: Regioselective Allylation of Carbon Electrophiles with Alkenylsilanes under Dual Catalysis by Cationic Platinum(II) Species

Autor: Masahiro Horikoshi, Ryosuke Kizu, Junji Ichikawa, Gen Inoue, Hidenori Kinoshita, Katsukiyo Miura, Masayuki Fujimoto, Akira Hosomi, Masanori Saito
Rok vydání: 2016
Předmět:
Zdroj: ChemInform. 47
ISSN: 0931-7597
Popis: Three procedures for the allylation of acetals and aminals with (Z)-1-trimethylsilylalkenes are elaborated: direct allylation, three-component reaction of the respective aldehyde, orthoformate or carbamate, and silylalkene, and pretreatment of the silylalkene followed by addition of acetal or aminal.
Databáze: OpenAIRE