Aerobic oxidation of isosorbide and isomannide employing TEMPO/laccase

Autor: Thomas Dr. Haas, Walter M. F. Fabian, Nina G. Schmidt, Kurt Faber, Johannes Gross, Aashrita Rajagopalan, Michael Fuchs, Wolfgang Kroutil, Katharina Tauber, Jan Pfeffer
Rok vydání: 2014
Předmět:
Zdroj: Green Chem.. 16:2117-2121
ISSN: 1463-9270
1463-9262
Popis: The oxidation of the renewable diols isosorbide and isomannide was successfully achieved using a TEMPO/laccase system. Furthermore, various TEMPO-derivatives were tested leading to conversions of up to >99% for the oxidation of isosorbide, isomannide, indanol and a halohydrin to the corresponding ketone.
Databáze: OpenAIRE