Synthesis, characterization, and reaction chemistry of a bis(iodosylbenzene)metalloporphyrin complex, [PhI(OAc)O]2MnIVTPP. A complex possessing a five-electron oxidation capability

Autor:	Craig L. Hill, John A. Smegal
Rok vydání:	1983
Předmět:	Chemistry Inorganic chemistry Kinetics chemistry.chemical_element General Chemistry Manganese Biochemistry Chemical reaction Catalysis Ion Chemical kinetics Hydroxylation chemistry.chemical_compound Colloid and Surface Chemistry Transition metal Halogen Polymer chemistry
Zdroj:	Journal of the American Chemical Society. 105:2920-2922
ISSN:	1520-5126 0002-7863
DOI:	10.1021/ja00347a079
Popis:	The synthesis, characterization, and reaction chemistry of a new type of manganese(IV) complex, (PhI(OAc)O)/sub 2/Mn/sup IV/TPP, which hydroxylates alkanes and epoxidizes olefins is reported. This complex contains both a transition metal (Mn) and a nonmetal ion (I) in unusual oxidation states. The high-valent iodine and manganese atoms provide this complex with a five-electron oxidation capability.
Databáze:	OpenAIRE
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