Processes involved in luminol oxidation accompanied by chemiluminescence

Autor:	A. P. Purmal, T. P. Vorob'eva, V. L. Tal'roze, E. L. Frankevich, B. A. Rusin, Yu. V. Koltypin, Yu. N. Kozlov
Rok vydání:	1976
Předmět:	Hypochlorous acid Chemistry Inorganic chemistry General Chemistry Limiting Photochemistry Luminol law.invention Hydrolysis chemistry.chemical_compound Reaction rate constant law Sodium hypochlorite Chemiluminescence
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 25:2043-2048
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf02659512
Popis:	1. Spectrophotometric studies have been carried out on the oxidation of luminol by sodium hypochlorite, working with solutions of various concentrations and pH values. Formation of the final product is the result of a series of successive reactions. The limiting step in the process is the two-electron oxidation of luminol (monoanion) by hypochlorous acid with the formation diazoquinone. 2. The bimolecular rate constant for the limiting step has been evaluated. 3. It has been shown that an unstable intermediate, blue-violet in color (pH
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::fa6012cf9cd82cc782e6dc4b724115dd https://doi.org/10.1007/bf02659512 Zobrazit plný text záznamu Full text from SpringerLink