Oxidation of heterocyclic thioureas to form benzothiazoles and their copper(II) complexes

Autor:	Douglas X. West, Lisa F. Szczepura, Joyce Kelley, Karen I. Goldberg, James M. Giesen, Werner Kaminsky
Rok vydání:	2003
Předmět:	Ethanol Stereochemistry Aryl Organic Chemistry chemistry.chemical_element Crystal structure Copper Nitrogen Medicinal chemistry Analytical Chemistry Inorganic Chemistry chemistry.chemical_compound chemistry Group (periodic table) Pyridine Thiazole Spectroscopy
Zdroj:	Journal of Molecular Structure. 646:95-102
ISSN:	0022-2860
DOI:	10.1016/s0022-2860(02)00592-6
Popis:	N-2-(5-picolyl)-N 0 -methoxyphenylthioureas are oxidized in alkaline ethanol solution by copper(II) to 2-(5-picolylamino)methoxybenzothiazoles and on air oxidation form [Cu(N,N)2] complexes. Coordination is via the pyridine and thiazole nitrogen atoms. Structural studies show these four-coordinate complexes are closer to tetrahedral than planar and show structural differences based on the position of the methoxy group on the aryl group. q 2002 Elsevier Science B.V. All rights reserved.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::fa1ed8be643c3b5f1937e646a02c553d https://doi.org/10.1016/s0022-2860(02)00592-6 Zobrazit plný text záznamu Full Text from ScienceDirect