ChemInform Abstract: Sol-Gel Synthesis of the Magnetically Frustrated Oxides Sr2FeSbO6 and SrLaFeSnO6

Autor:	Jason P. Hodges, Andrew J. Herod, Peter D. Battle, Terence C. Gibb
Rok vydání:	2010
Předmět:	Diffraction SQUID Crystallography Period (periodic table) Chemistry law Magnetometer Phase (matter) Mössbauer spectroscopy General Medicine Sol-gel law.invention Monoclinic crystal system
Zdroj:	ChemInform. 26
ISSN:	0931-7597
DOI:	10.1002/chin.199523017
Popis:	The use of the sol–gel synthesis method has been extended to include the preparation of stannates and antimonates from a citrate precursor. Samples of SrLaFeSnO6 and Sr2FeSbO6 have been prepared in a few hours. The structural and magnetic properties of the former are compared with those of a sample prepared over a period of several days by a solid-state route. The properties of Sr2FeSbO6 have been investigated by a combination of X-ray diffraction Mossbauer spectroscopy and SQUID magnetometry. The monoclinic perovskite structure has a partially (84%) ordered distribution of Fe and Sb cations over the six-coordinate sites; a transition to a magnetically frustrated phase occurs at 36 K.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::fa1afecd25cdf7622ca909efe8ec4207 https://doi.org/10.1002/chin.199523017 Zobrazit plný text záznamu Plný text