Convenient One Pot Preparation of Acylated Phosphinimines and Aminophosphonium Salts From the Versatile Triphenylphosphonium and Lithium Azayldiide Ph3P=N−Li

Autor:	Amer Hammami, Eric Manginot, Henri-Jean Cristau, E. Torreilles
Rok vydání:	1998
Předmět:	Inorganic Chemistry Acylation chemistry Organic Chemistry chemistry.chemical_element Organic chemistry Lithium Alkylation Biochemistry Gaseous ammonia
Zdroj:	Phosphorus, Sulfur, and Silicon and the Related Elements. 134:475-486
ISSN:	1563-5325 1042-6507
DOI:	10.1080/10426509808545488
Popis:	Starting from gaseous ammonia, through two multisteps reactions, either acylation or alkylation reactions, we have access to different N-substituted aminophosphonium salts, precursors of amines. Preparation and use of the intermediate, the triphenylphosphonium and lithium azayldiide Ph3P=N-Li 1, were realized in “one pot”.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f9f840b5ed7bc7890c0211312b2a89c1 https://doi.org/10.1080/10426509808545488 Zobrazit plný text záznamu