Synthesis and structure of tris[(2-alkoxymethyl)phenyl]germanes and tris[(2-methylthiomethyl)phenyl]germane
Autor: | Keiichiro Ogawa, Katsumi Tanaka, Jun Harada, Toschitake Iwamoto, Hidetaka Yuge, Hiroyuki Yamamoto, Yoshito Takeuchi |
---|---|
Rok vydání: | 1998 |
Předmět: | |
Zdroj: | Tetrahedron. 54:9811-9822 |
ISSN: | 0040-4020 |
DOI: | 10.1016/s0040-4020(98)00535-3 |
Popis: | Tris[(2-alkoxymethyl)phenyl]germanes and tris[(2-methylthiomethyl)phenyl]germane were prepared and their structures were investigated by means of X-ray crystallographic analysis and 73Ge NMR spectra, which indicated incipient dative bonding between germanium and sulfur or oxygen atoms to make the germanium atom hexavalent and heptavalent, respectively. |
Databáze: | OpenAIRE |
Externí odkaz: |