Adhesion properties of benzoyl peroxide crosslinked epoxidized natural rubber (ENR 25)-based pressure-sensitive adhesives
Autor: | B.T. Poh, N.H. Suid |
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Rok vydání: | 2014 |
Předmět: |
010407 polymers
Materials science Polymers and Plastics General Chemical Engineering 02 engineering and technology Benzoyl peroxide engineering.material 01 natural sciences chemistry.chemical_compound Coating Natural rubber Materials Chemistry medicine Shear strength Composite material Marketing organic chemicals technology industry and agriculture General Chemistry Adhesion 021001 nanoscience & nanotechnology Toluene 0104 chemical sciences Solvent chemistry visual_art engineering visual_art.visual_art_medium Adhesive 0210 nano-technology medicine.drug |
Zdroj: | Journal of Vinyl and Additive Technology. 22:8-12 |
ISSN: | 1083-5601 |
DOI: | 10.1002/vnl.21405 |
Popis: | Adhesion properties of crosslinked (epoxidized natural rubber)-based adhesives were studied by using coumarone-indene, benzoyl peroxide, and toluene as tackifying resin, crosslinking agent, and solvent, respectively. The adhesion properties were measured by a Lloyd Adhesion Tester operating at 30 cm min−1. Results show that loop tackiness and peel strength pass through a maximum value at 1 phr (parts by weight per hundred parts of resin) of benzoyl peroxide concentration, an observation that is attributed to the optimum crosslinking of epoxidized natural rubber whereby optimum cohesive and adhesive strength are obtained. However, shear strength increases with increasing benzoyl peroxide concentration wherein the higher rate of increase is observed between 0 and 1 phr of benzoyl peroxide content. This observation is associated with the steady increase in cohesive strength as crosslinking is increased. In all cases, the adhesion properties of adhesives increased with increasing coating thickness. J. VINYL ADDIT. TECHNOL., 2014. © 2014 Society of Plastics Engineers |
Databáze: | OpenAIRE |
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