13C NMR study of Ca@C74: the cage structure and the site-hopping motion of a Ca atom inside the cage

Autor:	Takeshi Kodama, Hiroyuki Nishikawa, Isao Ikemoto, Ryosuke Fujii, Yoko Miyake, Koichi Kikuchi, Shinzo Suzuki, Yohji Achiba
Rok vydání:	2004
Předmět:	Crystallography Chemistry Carbon-13 NMR satellite Atom Physics::Atomic and Molecular Clusters General Physics and Astronomy Physical and Theoretical Chemistry Carbon-13 NMR Cage Spectral line Line (formation)
Zdroj:	Chemical Physics Letters. 399:94-97
ISSN:	0009-2614
DOI:	10.1016/j.cplett.2004.08.146
Popis:	The 13 C NMR spectra of Ca@C 74 have been measured at 22 and 70 °C. The cage symmetry is assigned to be D 3h . Two distinct features of the 13 C NMR spectra, different linewidths of each line and line sharpening at higher temperature, indicate that the Ca atom hops between the several stable sites inside the D 3h cage.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f9a7d1cebb9e5da9c7234001966f92e0 https://doi.org/10.1016/j.cplett.2004.08.146 Zobrazit plný text záznamu Full Text from ScienceDirect