Highly Regioselective and Active Rhodium/Bisphosphite Catalytic System for Isomerization–Hydroformylation of 2-Butene

Autor:	Min Mo, Cong-Ye Zheng, Ruixiang Li, Hua Chen, Maolin Yuan, Haiyan Fu, Tao Yi
Rok vydání:	2011
Předmět:	chemistry.chemical_classification chemistry.chemical_element Regioselectivity Homogeneous catalysis General Chemistry Aldehyde Catalysis Rhodium chemistry Yield (chemistry) Organic chemistry Selectivity Isomerization Hydroformylation
Zdroj:	Catalysis Letters. 142:238-242
ISSN:	1572-879X 1011-372X
Popis:	The formation of linear aldehyde from isomerization–hydroformylation of 2-butene represents an important subject and current task in industry. Both high activity and excellent regioselectivity were achieved in the rhodium-catalyzed 2-butene isomerization–hydroformylation with 2,2′-bis(dipyrrolylphosphinooxy)-1,1′-(±)-binaphthyl (1) as ligand. Bulky phosphite with electron-withdrawing pyrrol groups dramatically improved the selectivity of linear product, and a good yield of 90.5% aldehydes was obtained with an excellent linear aldehyde regioselectivity of 95.3% under optimized condition. Bulky phosphite with electron-withdrawing pyrrol groups dramatically improved the selective of linear product, and an excellent yield of 90.5% aldehydes with 95.3% regioselectivity of linear aldehyde was obtained in the Rh-catalyzed isomerization–hydroformylation of 2-butene in the presence of ligand 1.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f997a56d51e6131cd8f400b2c7a9b876 https://doi.org/10.1007/s10562-011-0751-7 Zobrazit plný text záznamu Full text from SpringerLink