Synthesis and structure of an ether-bridged double ladder compound: potential in host–guest chemistry

Autor:	Edward R. T. Tiekink, Jens Beckmann, Dainis Dakternieks, Fong Sheen Kuan, Andrew Duthie
Rok vydání:	2003
Předmět:	Inorganic Chemistry Crystallography chemistry.chemical_compound Chemistry Stereochemistry Organic Chemistry Materials Chemistry Solid-state Ether Physical and Theoretical Chemistry Host–guest chemistry Biochemistry Dissociation (chemistry)
Zdroj:	Journal of Organometallic Chemistry. 688:56-61
ISSN:	0022-328X
DOI:	10.1016/j.jorganchem.2003.08.029
Popis:	The synthesis of the first example of an organotin double ladder ( 6 ) containing a functional group within the spacer is reported. In the solid state, compound 6 shows an interlaminar cavity whose size and shape suggest the possibility of host–guest chemistry. 119 Sn-NMR and ESMS show that compound 6 undergoes extensive dissociation in solution. ESMS of compound 6 to which have been added Li + , Na + , Mg 2+ or Cu 2+ show only minimal interaction.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f996b8d8f92c254c592405a4455ea2d2 https://doi.org/10.1016/j.jorganchem.2003.08.029 Zobrazit plný text záznamu Full Text from ScienceDirect