Polarity of para-disubstituted benzene derivatives: a correlation analysis of the substituent effect

Autor:	Alexey N. Egorochkin, N. M. Khamaletdinova, Olga V. Kuznetsova
Rok vydání:	2019
Předmět:	chemistry.chemical_compound Dipole chemistry Polarizability Polarity (physics) Correlation analysis Substituent Molecule General Chemistry Resonance (chemistry) Acceptor Medicinal chemistry
Zdroj:	Russian Chemical Bulletin. 68:1860-1865
ISSN:	1573-9171 1066-5285
DOI:	10.1007/s11172-019-2636-7
Popis:	The article is concerned with the influence of resonance donor substituents RD on the dipole moments μ of molecules 1,4-RDC6H4RA containing resonance acceptor groups RA (CF3, CN, COCH3, NO2 or COH) and grouped in five reaction (indicator) series. Generally, the μ values depend on the inductive, resonance, and polarizability effects of the substituents RD. Strengthening of the resonance acceptor properties of the RA groups leads to weaker conjugation between the substituents RD and the π-system.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f9920c3a77515ac9bf546b5d56ef9b39 https://doi.org/10.1007/s11172-019-2636-7 Zobrazit plný text záznamu Full text from SpringerLink