Synthesis of molybdenum arene complexes containing amide-derived heterodifunctional P,O ligands

Autor:	Malcolm L. H. Green, Xavier Morise, Andrew R. Cowley, Pierre Braunstein, Neale G. Jones, Ino Vei
Rok vydání:	2002
Předmět:	chemistry.chemical_compound Crystallography Chemistry Molybdenum Ligand Amide Cationic polymerization chemistry.chemical_element General Chemistry Crystal structure
Zdroj:	Journal of the Chemical Society, Dalton Transactions. :1487-1493
ISSN:	1364-5447 1472-7773
DOI:	10.1039/b105957m
Popis:	The reactions of the amide-derived ligands Ph2PN(R)C(O)CH3 (R = H, CH3) with the molybdenum arene complexes [Mo(η3-C3H5)(μ-Cl)(η6-C6H5R)]2 (R = H, CH3) have been investigated. A series of complexes in which the functional ligand displays η1-phosphine, η2-acetamidophosphine and η2-phosphinoiminolate coordination have been synthesised and characterised. The crystal structures of the cationic compounds [Mo(η3-C3H5)(η6-C6H6){Ph2PN(R)C(O)CH3-κ2P,O}][PF6] (R = H, CH3) have been determined. The first example of a structurally characterised phosphinoiminolate complex [Mo(η3-C3H5)(η6-C6H6){Ph2PNC(O)CH3-κ2P,O}] is also reported.
Databáze:	OpenAIRE
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