Cobalt(iii)–salen decorated stereoregular optically active helical polyisocyanides enable highly effective cooperative asymmetric catalysis toward the kinetic resolution of epoxides

Autor: Shu-Ming Kang, Xue Song, Ting-Ting Zhang, Lei Xu, Yuan-Yuan Zhu, Zong-Quan Wu
Rok vydání: 2023
Předmět:
Zdroj: Inorganic Chemistry Frontiers. 10:3345-3358
ISSN: 2052-1553
DOI: 10.1039/d3qi00384a
Popis: The decoration of Co(iii)–salen onto stereoregular optically active helical polyisocyanides considerably increased efficiency and enantioselectivity of kinetic resolution of epoxides through improved cooperative asymmetric catalysis mode.
Databáze: OpenAIRE