Evaluation of individual kinetic constants from experimental data on the kinetics of a polymer-analogous reaction

Autor:	O.V. Noa, A.N. Olonovskii, Nicolai A. Platé, L.B. Stroganov
Rok vydání:	1989
Předmět:	chemistry.chemical_classification Materials science Fortran Group (mathematics) Kinetics General Engineering Thermodynamics Experimental data Polymer First order Kinetic energy Square (algebra) chemistry computer computer.programming_language
Zdroj:	Polymer Science U.S.S.R.. 31:1412-1420
ISSN:	0032-3950
DOI:	10.1016/0032-3950(89)90174-3
Popis:	A method was developed for the determination of individual kinetic constants of an irreversible first order polymer-analogous reaction, involving a “neighbouring group” effect. The method is based on the minimalization of the sum of square deviations between experimental and computer generated kinetic data. The ambuguity of the method is demonstrated, and an algorithm is proposed generating all sets of constants corresponding to the experiment. The method is presented in the form of a FORTRAN program for the computer BESM-6. Depending on experimental accuracy, ranges are defined where the method yields unambiguous results.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f95bf6b836f7268447b0a4c6f30e2195 https://doi.org/10.1016/0032-3950(89)90174-3 Zobrazit plný text záznamu