Atomic scale elemental mapping of light elements in multilayered perovskite coatings

Autor: Corneliu Ghica, Valentin S. Teodorescu, R.F. Negrea
Rok vydání: 2015
Předmět:
Zdroj: Applied Surface Science. 355:250-255
ISSN: 0169-4332
DOI: 10.1016/j.apsusc.2015.07.106
Popis: Spherical aberration corrected transmission electron microscopes offer unprecedented capabilities in materials structural characterization down to atomic resolution. Electron energy loss spectroscopy (EELS) – spectrum imaging (SI) and annular bright field (ABF) imaging allow to simultaneously identify both the position and nature of the atomic species in a crystalline material. These techniques, along with conventional high-resolution transmission electron microscopy are particularly useful in heterostructures interfaces like epitaxial multilayers characterization, for identifying possible atomic interdiffusion at sub-nanometric scale. This paper presents the structural and compositional microanalysis down to atomic resolution of an epitaxial BaTiO3/SrRuO3/SrTiO3 ferroelectric heterostructure using complex complementary analytical electron microscopy techniques. The atomic arrangement of both heavy and light atomic species across the interfaces in the BaTiO3/SrRuO3/SrTiO3 heterostructures is revealed.
Databáze: OpenAIRE