Separation of Lutidine Isomers by Selective Enclathration

Autor:	Luigi R. Nassimbeni, Susan A. Bourne, Jacky S. Bouanga Boudiombo, Hong Su, Edwin Weber
Rok vydání:	2018
Předmět:	Biphenyl Crystallography chemistry.chemical_compound chemistry 010405 organic chemistry Proton NMR General Materials Science General Chemistry 010402 general chemistry Condensed Matter Physics Thermal analysis 01 natural sciences 0104 chemical sciences
Zdroj:	Crystal Growth & Design. 18:2620-2627
ISSN:	1528-7505 1528-7483
Popis:	The host compound 3,3′-bis(9-hydroxy-9-fluorenyl)-2–2′-binaphthyl, H1, has been employed to separate the six isomers of lutidine. Competition experiments showed that the preference for enclathration is in the sequence 3,4-LUT > 2,6-LUT > 2,3-LUT > 2,5-LUT > 2,4-LUT ≈ 3,5-LUT. The structures yielded results that agree with the 1H NMR analyses and with the thermal analysis. The effects of mixed hosts and vapor-phase competitions were briefly explored with two extra hosts, namely, 2,2′-bis(1-hydroxy-4,5-dihydro-2:3,6:7-dibenzocycloheptadien-1-yl)biphenyl (H2) or 3,3′-bis(di-p-tolylhydroxymethyl)-1,1′-binaphthyl (H3).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f91463d85f2c28c8bd842a3207df33b2 https://doi.org/10.1021/acs.cgd.8b00251 Zobrazit plný text záznamu