About the structure of cellulose: debating the Lindman hypothesis

Autor: Yoshiharu Nishiyama, Walther Burchard, R. Malcolm Brown, Alfred D. French, Wolfgang G. Glasser, Rajai H. Atalla, Dieter Klemm, John Blackwell
Rok vydání: 2012
Předmět:
Zdroj: Cellulose. 19:589-598
ISSN: 1572-882X
0969-0239
DOI: 10.1007/s10570-012-9691-7
Popis: The hypothesis advanced in this issue of CELLULOSE [Springer] by Bjorn Lindman, which asserts that the solubility or insolubility characteristics of cellulose are significantly based upon amphiphilic and hydrophobic molecular interactions, is debated by cellulose scientists with a wide range of experiences representing a variety of scientific disciplines. The hypothesis is based on the consideration of some fundamental polymer physicochemical principles and some widely recognized inconsistencies in behavior. The assertion that little-recognized (or under-estimated) hydrophobic interactions have been the reason for a tardy development of cellulose solvents provides the platform for a debate in the hope that new scientific endeavors are stimulated on this important topic.
Databáze: OpenAIRE