Discrimination between pentose oligosaccharides containingD-xylopyranose orL-arabinofuranose as non-reducing terminal residue using fast atom bombardment mass spectrometry

Autor:	Vladimír Kováčik, Ján Hirsch, Vladimír Pätoprstý
Rok vydání:	2001
Předmět:	chemistry.chemical_classification Ring size chemistry Aldose Stereochemistry Mass spectrum Tetrasaccharide Oligosaccharide Fast atom bombardment Mass spectrometry Spectroscopy Dissociation (chemistry)
Zdroj:	Journal of Mass Spectrometry. 36:379-383
ISSN:	1076-5174
DOI:	10.1002/jms.138
Popis:	Collisional-induced dissociation (CID) mass spectra of the [M + H](+) and [M - H](-) ions obtained under fast atom bombardment conditions of a number of methyl glycoside di-, tri- and tetrasaccharides, containing D-xylopyranosyl and/or L-arabinofuranosyl residues at the non-reducing terminus, do not provide information about their ring size. This information could only be obtained from a careful comparison of the intensity ratio of the [M + Na - 90](+) and [M + Na - 104](+) ions ((0,2)X(t)/(1,5)X(t)) in the high-energy CID spectra of the sodium-cationized di-, tri- and probably also tetrasaccharide compounds.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f8df26a471a81594e6c95bbcc74850e0 https://doi.org/10.1002/jms.138 Zobrazit plný text záznamu Plný text