Synthesis of gallium acetylide complexes NaGa(C?CR)4 by metallization of 1-alkynes with sodium gallohydride in the presence of secondary amines

Autor:	V. S. Kolesov, V. V. Gavrilenko, L. I. Zakharkin
Rok vydání:	1981
Předmět:	chemistry.chemical_compound C5H10 chemistry Acetylide Sodium Amide Polymer chemistry chemistry.chemical_element Organic chemistry Amine gas treating General Chemistry Gallium
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 30:1099-1102
ISSN:	1573-9171 0568-5230
Popis:	1. The interaction of NaGaH4 with 1-alkynes in the presence of secondary amines at 110–120° gave gallium acetylide complexes with a general formula NaGa(C≡CR)4, where R=C3H7, C4H9, C6H13, C6H5. 2. The reaction between NaGaH4 and secondary amines was studied, and compounds with the general formula NaGaHn(NR2)4−n, n=1,2 were obtained, where R=CH3, C2H5, C5H10. 3. The reaction between NaGaH4 and 1-alkynes in the presence of a secondary amine was shown to take place in a stepwise manner through the intermediate formation of amide derivatives of sodium gallohydride.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f8d96ce7e90932de7f6fc33f2725b53c https://doi.org/10.1007/bf00950304 Zobrazit plný text záznamu Full text from SpringerLink