anti-Carbometalation of Alkynyl Sulfides Using Indium Tribromide and Ketene Silyl Acetals

Autor:	Makoto Yasuda, Yoshihiro Nishimoto, Kyoungmin Kang, Kosuke Sakamoto
Rok vydání:	2020
Předmět:	chemistry.chemical_compound chemistry Nucleophile Silylation Regioselectivity chemistry.chemical_element Ketene General Chemistry Tribromide Medicinal chemistry Indium Carbometalation Organosilicon
Zdroj:	Chemistry Letters. 49:1136-1139
ISSN:	1348-0715 0366-7022
DOI:	10.1246/cl.200400
Popis:	We developed the regioselective anti-carbometalation of alkynyl sulfides via the use of InBr3 and organosilicon nucleophiles to give β-mercaptoalkenylindium compounds. The structure of β-mercaptoal...
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f8ced6015bedfd4c740a9086f6fa16b0 https://doi.org/10.1246/cl.200400 Zobrazit plný text záznamu