Reaction of dihalocarbenes with aryl and cyclopropyl derivatives of ethylene

Autor: R. N. Shafran, A. I. Ioffe, Oleg M. Nefedov
Rok vydání: 1977
Předmět:
Zdroj: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 26:2129-2133
ISSN: 1573-9171
0568-5230
DOI: 10.1007/bf00923634
Popis: The method of competitive reactions has been used to investigate the activity of p- and α-substituted styrenes and 1-substituted cyclopropylethylenes in reactions with dihalocarbenes. The weakening of the influence of the substituents on the activity of the double bond with their increasing nucleophilic properties has been demonstrated, and it has been concluded that there is a single mechanism underlying the reactions of dichlorocarbene with the olefins investigated.
Databáze: OpenAIRE