Synthesis and structure of new 2,4-dicyano-6-oxo-3-phenylbicyclo[3.2.1]octane-2,4-dicarboxylates

Autor: A. M. Magerramov, Victor V. Dotsenko, Nicolai A. Aksenov, Inna V. Aksenova, A. I. Ismiyev
Rok vydání: 2020
Předmět:
Zdroj: Russian Chemical Bulletin. 69:1938-1943
ISSN: 1573-9171
1066-5285
Popis: The sequential reaction of furfural with cyclic secondary amines and further with benzaldehyde and cyanoacetates affords new 2,4-dicyano-8-(R2N)-6-oxo-3-phenylbicyclo[3.2.1]-octane-2,4-dicarboxylates as rac-(1R,2R,3R,4S,5S,8R)-diastereomers. The structures of the reaction products were determined by X-ray diffraction.
Databáze: OpenAIRE