Living-like helix-sense-selective polymerization of an achiral substituted acetylene having bulky substituents

Autor:	Toyokazu Tsutsuba, Takeshi Namikoshi, Masahiro Teraguchi, Takashi Kaneko, Toshiki Aoki, Yu Zang, Kazuki Nakao, Hiroki Yotsuyanagi
Rok vydání:	2013
Předmět:	Living free-radical polymerization End-group Chain-growth polymerization Materials science Polymers and Plastics Polymerization Organic Chemistry Radical polymerization Polymer chemistry Materials Chemistry Cationic polymerization Living polymerization Degree of polymerization
Zdroj:	Polymer. 54:1729-1733
ISSN:	0032-3861
Popis:	By using a new achiral phenylacetylene having bulky substituents as a monomer, living-like helix-sense-selective polymerization ( HSSP ) has been achieved. This is the first example of the HSSP of substituted acetylenes where the degree of polymerization was controlled. The resulting one-handed helical living polymer initiated polymerization of a second monomer to successfully yield a block copolymer.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f89849ec2b89936e7d676ae961664766 https://doi.org/10.1016/j.polymer.2013.02.009 Zobrazit plný text záznamu Full Text from ScienceDirect