Measurement of the O2(b1Σg+→ a1Δg) transition probability by the method of intracavity laser spectroscopy

Autor: Nikolai P Vagin, Andrei A Ionin, Yu P Podmar'kov, Mikhail P. Frolov, Nikolai N Yuryshev, Igor' V Kochetov, Anatoly P. Napartovich
Rok vydání: 2005
Předmět:
Zdroj: Quantum Electronics. 35:378-384
ISSN: 1468-4799
1063-7818
Popis: The method of intracavity laser spectroscopy using a Co:MgF2 laser is applied to record the absorption spectra from the first excited a1Δg state of gaseous molecular oxygen at the a1Δg → b1Σg+ transition at 1.91 μm. The gas flow from a chemical singlet oxygen generator with a known concentration of singlet oxygen O2 (a1Δg) was supplied to the cavity of the Co:MgF2 laser. The absorption line intensities are measured for five spectral lines of the Q-branch of the 0–0 vibrational band for the a1Δg → b1Σg+ transition. The O2 (b1Σg+ → a1Δg) transition probability calculated from these data was (1.20 ± 0.25) × 10-3 s-1.
Databáze: OpenAIRE