Measurement of the O2(b1Σg+→ a1Δg) transition probability by the method of intracavity laser spectroscopy
Autor: | Nikolai P Vagin, Andrei A Ionin, Yu P Podmar'kov, Mikhail P. Frolov, Nikolai N Yuryshev, Igor' V Kochetov, Anatoly P. Napartovich |
---|---|
Rok vydání: | 2005 |
Předmět: |
Materials science
Absorption spectroscopy business.industry Singlet oxygen Halide chemistry.chemical_element Statistical and Nonlinear Physics Laser Oxygen Atomic and Molecular Physics and Optics Spectral line Electronic Optical and Magnetic Materials law.invention chemistry.chemical_compound Optics chemistry law Excited state Electrical and Electronic Engineering Atomic physics Spectroscopy business |
Zdroj: | Quantum Electronics. 35:378-384 |
ISSN: | 1468-4799 1063-7818 |
Popis: | The method of intracavity laser spectroscopy using a Co:MgF2 laser is applied to record the absorption spectra from the first excited a1Δg state of gaseous molecular oxygen at the a1Δg → b1Σg+ transition at 1.91 μm. The gas flow from a chemical singlet oxygen generator with a known concentration of singlet oxygen O2 (a1Δg) was supplied to the cavity of the Co:MgF2 laser. The absorption line intensities are measured for five spectral lines of the Q-branch of the 0–0 vibrational band for the a1Δg → b1Σg+ transition. The O2 (b1Σg+ → a1Δg) transition probability calculated from these data was (1.20 ± 0.25) × 10-3 s-1. |
Databáze: | OpenAIRE |
Externí odkaz: |