Effect of vibrational excitation on the reactivity of methyl fluoride with bromine atoms

Autor: N. K. Serdyuk, V. P. Strunin, E. N. Chesnokov, V. N. Panfilov
Rok vydání: 1976
Předmět:
Zdroj: Reaction Kinetics and Catalysis Letters. 5:37-41
ISSN: 1588-2837
0133-1736
DOI: 10.1007/bf02067430
Popis: The influence of non-equilibrium vibrational excitation of CH3F molecules on the rate of their reaction with bromine atoms has been investigated. A three-fold increace in the reaction rate has been registered at CH3F and Br2 pressures of 0.07 Torr and at 100°C. The increase is shown not to be associated with equilibrium thermal heating.
Databáze: OpenAIRE