Solid-state reactions in Y2O3:3Al2O3:4B2O3 system studied by FTIR spectroscopy and X-ray diffraction
Autor: | L. Kovács, E. Beregi, János Madarász, Andrea Watterich |
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Rok vydání: | 2000 |
Předmět: | |
Zdroj: | Vibrational Spectroscopy. 22:169-173 |
ISSN: | 0924-2031 |
DOI: | 10.1016/s0924-2031(99)00078-8 |
Popis: | In the Y 2 O 3 :3Al 2 O 3 :4B 2 O 3 system infrared absorption spectroscopy and X-ray diffraction have been used to study the solid-state reactions in the 600–1300°C temperature range. The expected YAl 3 (BO 3 ) 4 formation (whose optimum temperature is at about 1150°C) was proceeded and accompanied by the appearance of YBO 3 and Al 4 B 2 O 9 intermediate phases. At higher temperatures the Al 18 B 4 O 33 phase was also identified with both methods. Based on these results, some chemical reactions were suggested. |
Databáze: | OpenAIRE |
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