A new polymorph of dichlorido(1,10-phenanthroline)platinum(II)

Autor:	Luciana Maresca, Carmen R. Barone, Concetta Pacifico, Giovanni Natile
Rok vydání:	2011
Předmět:	Inorganic Chemistry chemistry.chemical_compound Crystallography chemistry Polymorphism (materials science) Phenanthroline Materials Chemistry chemistry.chemical_element Orthorhombic crystal system Physical and Theoretical Chemistry Platinum Monoclinic crystal system
Zdroj:	Inorganica Chimica Acta. 366:384-387
ISSN:	0020-1693
DOI:	10.1016/j.ica.2010.11.001
Popis:	A yet unreported polymorph of [PtCl2(1,10-phenanthroline)] was obtained by slow decomposition, in CH2Cl2 solution, of [Pt{CH2CH2N(CH2CH3)2-κC,κN}(1,10-phenanthroline)](ClO4). The structure of the new orthorhombic form, III, (space group Pna21), is described and compared to those of the two already reported forms, I and II, which are monoclinic (space group P21/c) and orthorhombic (space group Pca21), respectively [21] . Polymorph III appears to be the least stable of the three.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f876b2f0600be9d14bf15977b0b9c614 https://doi.org/10.1016/j.ica.2010.11.001 Zobrazit plný text záznamu Full Text from ScienceDirect