Synthesis and structural chemistry of metallo-xanthate anions (M=Zn, Sn, Bi)

Autor:	Saniyah Ali, Kieran C. Molloy, Gabriele Kociok-Köhn, A. ur Rehman
Rok vydání:	2009
Předmět:	Chemistry Organic Chemistry Inorganic chemistry chemistry.chemical_element Zinc Structural chemistry Analytical Chemistry Bismuth Ion Inorganic Chemistry Dodecahedron chemistry.chemical_compound Crystallography Monomer Xanthate Tin Spectroscopy
Zdroj:	Journal of Molecular Structure. 937:56-60
ISSN:	0022-2860
DOI:	10.1016/j.molstruc.2009.08.012
Popis:	The structures of the metallo-xanthate anions [Zn(S2COR)3]− (R = Et (1), Pri (2)), [Sn(S2COR)3]− (R = Et (3), Pri (4)), and [Bi(S2COPri)4]− (5) have been determined as their [Me4N]+ salts. The two zinc species differ in having either all S,S bonded ligands (1) or both S,S and S,O-ligation (2). The tin compounds are either monomeric (4) or weakly associated into dimers (3), while 5 adopts a monomeric dodecahedral structure.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::f87319ee758d5913183254c20740d697 https://doi.org/10.1016/j.molstruc.2009.08.012 Zobrazit plný text záznamu Full Text from ScienceDirect