| Popis: |
[17865-20-2] C9H15SiCl (MW 186.76) InChI = 1S/C9H15ClSi/c1-4-7-11(10,8-5-2)9-6-3/h4-6H,1-3,7-9H2 InChIKey = LMQNPINUXNVGGV-UHFFFAOYSA-N (dendrimer capping agent) Alternate Names: triallylchlorosilane, triallylsilyl chloride. Physical Data: bp 97–98° C (30 mmHg); d 0.9197 g cm−3, 1.4779. Solubility: sol organics (benzene, Et2O, CHCl3, DCM, THF, DMF). Form Supplied in: colorless liquid. Analysis of Reagent Purity: 1H NMR, 13C NMR, GC, HPLC. Preparative Methods: allylation of tetrachlorosilane viaGrignard addition of allylmagnesium chloride,1 treatment of triallylsilane with anhydrous CuCl2 under basic conditions in acetonitrile,2 or via allylation of tetrachlorosilane with allylsamarium bromide.3 Purification: fractional distillation under reduced pressure, bp 97–98°C @ 30 mmHg. Handling, Storage, and Precautions: toxic; use only in fume hood; reagent can be absorbed through skin; always wear gloves when handling this reagent. |
