Mechanisms of radiation-induced defect generation in fused silica

Autor: Ute Natura, Michael Kahlke, Gabriele Fasold, Rolf Martin, Oliver Sohr
Rok vydání: 2004
Předmět:
Zdroj: SPIE Proceedings.
ISSN: 0277-786X
DOI: 10.1117/12.521739
Popis: Excimer laser radiation changes the optical properties of fused silica. These changes include radiation induced absorption and changes of the index of refraction, which in turn determine the expected lifetime of silica lenses used in optical microlithography. A fully automated experimental setup designed for the marathon exposure of samples at low energy densities was employed. Measurements of the induced absorption, of the H 2 content using Raman spectroscopy as well as wavefront measurements were performed. A model to predict the aging behaviour of silica in optical microlithography systems due to defect generation has been developed for both ArF laser irradiation and KrF laser irradiation. The model includes linear and nonlinear defect generation, relaxation processes and the consumption of hydrogen and describes the radiation induced changes of the index of refraction, the increase as well as the decrease. The model calculations were derived by analytical and numerical methods. A very good agreement in the range of parameters used in the experiments is observed. Keywords: defect generation, fused silica, hydrogen consumption, hydrogen bonded SiOH, compaction, rarefaction
Databáze: OpenAIRE